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Pembuatan Lahan Percontohan Tanaman Padi (Oriza Sativa L.) melalui Recovery Logam Berat
DOI:
https://doi.org/10.22437/chp.v2i2.4513Keywords:
sintesis, material AKHS, merkuri, emas, Oriza sativa.LAbstract
Telah dilakukan sintesis material amonium kuaterner hibrida silika (AKHS) dari abu sekam padi (ASP) sebagai prekursor silika. Proses modifikasi silika dengan gugus amin digunakan 3-aminopropriltrimetoksisilan (3-APTMS) untuk membentuk silika termodifikasi amin (STA). Proses reaksi metilasi digunakan metil iodida dengan pelarut dimetil formamida (DMF) dan toluena, sehingga terbentuk material AKHS. Karakterisasi dilakukan dengan spektroskopi infra merah (FTIR) dan difraksi sinar-X (XRD). Morfologi permukaan dan komposisi unsur diidentifikasi dengan SEM-EDX. Pengaruh pH larutan diperoleh pada pH optimum untuk ion Au(III) dan Hg(II) berturut-turut pada pH 3 dan 5. Logam berat mempengaruhi pertumbuhan padi (Oriza Sativa L.) pada lahan bekas penambangan emas.
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References
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Ngatijo, Nuryono, Narsito and Rusdiarso, B., 2013, Synthesis of Silica Modified with Quaternary Ammonium and its Application for Solid Phase Extraction of Au(III) ion, IPCBC, 56-61.
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Rusdiarso, B., 2007, Studi Ekstraksi Pelarut Emas(III) dalam larutan Konsentrat Tembaga PT Freeport dengan 8- Methylxantin, Berkala MIPA UGM, 17(2), 15-21.
Sakti, S.C.W., Susanta, D., Nuryono, 2013 , Adsorption of gold(III) on ionic imprinted amino-silica hybrid prepared from rice hull ash, J. Pure and Applied Chem., 85(1), 211-216
Sarawade, P., Jim, J.K., Hilonga, A., Quang, D.V., Jean, J.J., and Kim, H.T., 2011, Unified formation disordered mesoporous silica, structure by means of templating organic additives, J. of Non-Crystaline Solids, 357, 2156-2162
Yu , Y., Yaddai-Mensah, J., and Losic, D., 2011, Chemical Functionalization of Diatom Silica Microparticles for Adsorption of Gold(III) Ions, J. Nanopar. and Nanotech., 11, 1-8.
Campos, E.A., Elfaya, A.S., Ferrari, R.T., and and Costa, C.M., 2001, Quaternary Ammonium Salts Immobilized on Silica Gel : Exchange Properties and Application as Potentiometric Sensor for Perchlorate Ions, J. Colloid and Interface Sci., 240, 97-140
Chang, X., Wang, X., Jiang, N., Zhain, Q.H.Y., Zhu, X., and HU, Z., 2008, Silica gel surface-imprinted solid-phase extraction of Zr(IV) from aqueous solutions, J. Microchim Acta, 162, 113-119.
Della, Ká¹»hn, I., and Hotza, D., 2002, Rice husk ash as an source for active silica production, Mater Lett., 57, 818-821.
Etine, M., and Walcarius, A., 2003, Analytical Investigastion of Chemical Reactivity and Stability of Aminopropyl Grafted Silica in Aqueous Medium, Talanta, 59, 1173-1188.
Fachiori, J.L., Pizzolato, T.M., and Bernenutti, E.V., 2001, FTIR thermal Analyis on Organofunctionalized Silica Gel, J. Braz. Chem. Soc., 12(2) 159-164.
Hastuti, S., Nuryono and Kuncaka, A., 2015, L-Arginine-modified silica for adsorption of gold(III), Indones J. Chem., 15(2), 108-115.
Kalapathy, U., Proctor, A., and Shultz, J., 2002, An improved method for production of silica from rice husk ash, Biores. Technol., 85, 285-289
Kalapathy, U., Proctor, A ., and Shultz, J., 2000, A simple method for production of pure silica from rice husk ash, Biosor. Technol. 73, 257-262.
Madrakian,T., Alkhami, A., Zolfigol, M.A., Solgi, M., J. , 2006, Separation, preconcentration and determination of silver from water samples using silica modified with 2,4,6-trimopholio-1,3,5-triazin, J. Hazard. Mat., B 128, 67-72.
Ngah, W.W.S., Teong, L.C., and Hanafiah, M.A.K.M., 2011, Adsorption of dyes and heavy metal ions by chitosan composites: A review., Carbohydrate Polymer, 83, 1446-1456.
Ngatijo, Nuryono, Narsito and Rusdiarso, B., 2013, Synthesis of Silica Modified with Quaternary Ammonium and its Application for Solid Phase Extraction of Au(III) ion, IPCBC, 56-61.
Nuryono, 2006, Adsorption thermodynamic of Cd(II), Ni(II) and Mg(II) on 3-Mercapto-1,2,4-triazole Immobilized Silica Gel, Indo. J. Chem., 6(1), 52-55.
Rusdiarso, B., 2007, Studi Ekstraksi Pelarut Emas(III) dalam larutan Konsentrat Tembaga PT Freeport dengan 8- Methylxantin, Berkala MIPA UGM, 17(2), 15-21.
Sakti, S.C.W., Susanta, D., Nuryono, 2013 , Adsorption of gold(III) on ionic imprinted amino-silica hybrid prepared from rice hull ash, J. Pure and Applied Chem., 85(1), 211-216
Sarawade, P., Jim, J.K., Hilonga, A., Quang, D.V., Jean, J.J., and Kim, H.T., 2011, Unified formation disordered mesoporous silica, structure by means of templating organic additives, J. of Non-Crystaline Solids, 357, 2156-2162
Yu , Y., Yaddai-Mensah, J., and Losic, D., 2011, Chemical Functionalization of Diatom Silica Microparticles for Adsorption of Gold(III) Ions, J. Nanopar. and Nanotech., 11, 1-8.
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2018-02-07
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- 2018-02-07 (1)
- 2018-02-07 (1)
How to Cite
Pembuatan Lahan Percontohan Tanaman Padi (Oriza Sativa L.) melalui Recovery Logam Berat. (2018). Chempublish Journal, 2(2), 1-10. https://doi.org/10.22437/chp.v2i2.4513
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