A Novel Synthesis Route and Functional Group Analysis by FTIR Spectroscopy of Graphene Oxide from Indigenous Coal and Graphite

Authors

  • Lucky Zaehir Maulana Department of Physics, Universitas Jambi, Jambi, Indonesia
  • V. A Nanda Department of Physics, Universitas Jambi, Jambi, Indonesia
  • Rista Mutia Anggraini Department of Physics, Universitas Jambi, Jambi, Indonesia
  • Muhammad Ficky Afrianto Department of Physics, Universitas Jambi, Jambi, Indonesia
  • Fiqri Al Faruqi Department of Chemistry, Universitas Jambi, Jambi, Indonesia
  • Febri Berthalita Pujaningsih Department of Physics, Universitas Jambi, Jambi, Indonesia
  • Alrizal Department of Physics, Universitas Jambi, Jambi, Indonesia
  • Willy Bima Alfajri Department of Inforamtion Systems, Universitas Jambi, Jambi, Indonesia
  • Frastica Deswardani Department of Physics, Universitas Jambi, Jambi, Indonesia

DOI:

https://doi.org/10.22437/proca.v2i2.55564

Keywords:

Graphene oxide, Nanomaterial

Abstract

This study develops a novel synthesis route for producing Graphene Oxide (GO) using local Jambi coal and commercial graphite as carbon precursors through the Modified Hummers method. The objective of this research is to evaluate the success of the oxidation process and identify the oxygen-containing functional groups formed in the synthesized GO using Fourier Transform Infrared (FTIR) Spectroscopy. Three sample variations were prepared: coal-based GO (GOC), graphite-based GO (GOG), and coal–graphite mixture (GOGC). The FTIR results reveal the presence of characteristic GO functional groups, including –OH, C=C, C–O, C–OH, and C–O–C. The highest oxidation level was observed in the graphite-based sample, while the mixed sample exhibited a lower oxidation degree. These findings confirm that local coal can serve as a viable alternative carbon source for GO synthesis, offering added value to local resources and supporting the development of carbon-based advanced materials.

References

1. Anisa H, Yusuf M, Nasir S. Karakterisasi batubara Jambi untuk peningkatan kualitas batubara melalui radiasi gelombang mikro: characterization of Jambi coal for coal quality improvement using microwave radiation. Jurnal Pertambangan. 2020;4(4). Available from: http://ejournal.ft.unsri.ac.id/index.php/JP

2. Aziz MA, Wahyuni S, Fadila H, Fitriyah F, Sulastri S, Luktyansyah IM, et al. Characterization of low-rank coal from Jambi and several regions in Indonesia as raw material for humate fertilizer. Journal of Mineral and Coal Technology. 2022;18(1):1-11. doi:10.30556/jtmb.Vol18.No1.2022.1222

3. Bete YI, Bukit M, Zicko A, Dan J, Pingak RK. Kajian awal sifat optik graphene oxide berbahan dasar arang tongkol jagung yang disintesis dengan metode liquid phase exfoliation (LPE). Jurnal Fisika. 2019;4(2):2657-1900.

4. Díaz A, López M, Herrera R. Synthesis and functional group identification of graphene oxide via FTIR. Carbon Letters. 2020;34(4):221-229.

5. Fathy A, Hassan M, Salem S. Drying techniques in graphene oxide production: influence on structure and oxygen ratio. Journal of Advanced Materials Processing. 2024;18(1):101-112.

6. Ham H, Choi S, Park J. Improved oxidation methods for graphene oxide production. Materials Chemistry and Physics. 2014;143(2):795-802.

7. Hanifah R, Putra H, Syah R. Graphene oxide from graphite powder as fuel cell precursor. Journal of Energy Materials. 2017;9(3):133-140.

8. Hortigüela M, García P, Alonso F. Effect of oven temperature on graphene oxide microstructure. Journal of Applied Nanoscience. 2020;15(2):87-96.

9. Khalili D. Graphene oxide: a promising carbocatalyst for the regioselective thiocyanation of aromatic amines, phenols, anisols and enolizable ketones by hydrogen peroxide/KSCN in water. New Journal of Chemistry (ESI). 2016.

10. Mehmood Z, Shah SAA, Omer S, Idrees R, Saeed S. Scalable synthesis of high-quality reduced graphene oxide with a large C/O ratio and its dispersion in a chemically modified polyimide matrix for electromagnetic interference shielding applications. RSC Advances. 2024;14:7641-7654.

11. Pacheco Flores de Valgaz A, Salcedo Cajas G, Rivas Fermín A. From rice husk to graphene: exploring the effect of calcination and leaching. Lecture Notes in Networks and Systems. 2025;1331:271-281. doi:10.1007/978-3-031-87065-1_25

12. Purwandari E, Santoso T, Wijaya H. Coal-derived carbon for graphene synthesis in energy applications. Indonesian Journal of Materials. 2020;11(1):24-32.

13. Sargin M, Kaya Ö, Demir B. Oven drying behavior of graphene oxide and its structural implications. International Journal of Carbon Science. 2022;6(3):142-150.

14. Singh P, Dastgheib S. Role of drying conditions on layer stability of graphene oxide. Journal of Carbon Technologies. 2023;10(1):33-41.

15. Sun L, Fugetsu B. Massive production of graphene oxide from expanded graphite. Materials Letters. 2013;109:207-210. doi:10.1016/j.matlet.2013.07.072

16. Tabish TA, Pranjol MZI, Horsell DW, Rahat AAM, Whatmore JL, Winyard PG, et al. Graphene oxide-based targeting of extracellular cathepsin D and cathepsin L as a novel anti-metastatic enzyme cancer therapy. Cancers. 2019;11(3):319.

17. Thangaraj B, Mumtaz F, Abbas Y, Anjum DH, Solomon PR, Hassan J. Synthesis of graphene oxide from sugarcane dry leaves by two-stage pyrolysis. Molecules. 2023;28(8). doi:10.3390/molecules28083329

18. Widianto E, Maulana LZ, Suharyadi E, Giglia A, Koshmak K, Nannarone S, et al. High-energy excitonic effects in single-layer graphene. Physical Review Materials. 2024;8(6):065201.

19. Xing Y, Gui X, Liu J, Cao Y, Zhang Y, Li S. Flotation behavior of hard-to-separate and high-ash fine coal. Physicochemical Problems of Mineral Processing. 2016;52(2):703-717. doi:10.5277/ppmp160215

20. Zhang X, Zhang G, Wang F, Chi H. Evolution of oxygen content of graphene oxide for humidity sensing. Molecules. 2024;29(16):3741.

21. Zhang K, Zhang H, Liu L, Yang Y, Liu L, Liu Q. Dispersibility of kaolinite-rich coal gangue in rubber matrix and the mechanical properties and thermal stability of the composites. Minerals. 2021;11(12). doi:10.3390/min11121388

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Published

15-07-2026

How to Cite

Maulana, L. Z., Nanda, V. A., Anggraini, R. M., Afrianto, M. F., Faruqi, F. A., Pujaningsih, F. B., Alrizal, Alfajri, W. B., & Deswardani, F. (2026). A Novel Synthesis Route and Functional Group Analysis by FTIR Spectroscopy of Graphene Oxide from Indigenous Coal and Graphite. Proceedings Academic Universitas Jambi, 2(2), 247-253. https://doi.org/10.22437/proca.v2i2.55564